I'm an avid fan of Buffy and Angel and can't get enough fanfiction from that universe. My fav characters are Angel/Angelus, Spike, Lilah, Wesley, Fred/Illyria, Lindsey, Darla, Drusilla, Xander, Willow, Cordelia, Faith, Gunn, Tara, Giles, Anya, Dawn, Vampire Willow, Vampire Xander, and Doyle. My least favorite characters are Riley (he bored me), Buffy (she just gets on my nerves), Kennedy (not compatible with Willow at all), and Connor (well the teenage version anyway didn't like that whole storyline).
I'd say my alltime fav character would have to be Faith though followed by Spike.
pairings I enjoy
Spike/Willow (she's not gay she's bisexual)
Wesley/Faith (well the rugged Wesley anyway)
Xander/with any bad girl (love Dark or Vampire Xander)
hmm guess that's everyone
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